Product ID:RU 2000 REGULAR UNLEADED GASOLINE
MSDS Date:04/11/1990
FSC:9130
NIIN:00-148-7103
MSDS Number: BPMBK

SHELL OIL COMPANY

1 SHELL PLAZA
HOUSTON, TX 77001
US

Emergency Phone: 713-473-9461 (24 HOUR EMERGENCY)

Info Phone: 713-241-4819

Preparer: J. C. WILLETT

Cage: 54527

SHELL OIL COMPANY

2463 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25.0%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25.0%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0-5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 0-3%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-11%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ALKANES, CYCLOALKANES, ALKANES & AROMATIC HYDROCARBONS.

CAS: 68475-59-2

Fraction By Weight: BALANCE

LD50 LC50 Mixture:LD50 (ORAL RAT) IS >5 GM/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE-IRRITATING. SKIN-PROLONGED OR
REPEATED CONTACT CAN CAUSE DEFATTING & DRYING, RESULTING IN SKIN
IRRITATION & DERMATITIS. INHALE-IRRITATION TO THE NOSE, THROAT &
RESPIRATORY TRACT & MAY PRODUCE LIVE R & KIDNEY DAMAGE. INGEST-MAY
BE HARMFUL/FATAL IF SWALLOWED, RESULTING IN VOMITING OR ASPIRATION
PNEUMONITIS.
Explanation of Carcinogenicity:BENZENE IS SUSPECTED OF CARCINOGENIC
(LUKEMIA) POTENTIAL IN MAN AND IS LISTED BY IARC, NTP AND OSHA.
Effects of Overexposure:GIDDINESS, HEADACHE, DIZZINESS AND NAUSEA; IN
EXTREME CASES, UNCONCIOUSNESS AND DEATH MAY OCCUR. ASPIRATION
PNEUMONITIS CAN SHOW AS COUGHING, LABORED BREATHING AND CYANOSIS.
OTHER SIGN ARE CHANGES IN URINE OUTPUT, APPEARANCE OR EDEMA,
LOSSOF APPETITE, JAUNDICE AND PAIN IN THE UPPER ABDOMEN ON THE
RIGHT SIDE.
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT. IMPAIRED LIVER AND KIDNEY FUNCTIONS FROM PREEXISTING
DISORDERS MAY BE AGGRAVATED BY EXPOSURE.

First Aid:EYE-FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
SKIN-FLUSH WITH WATER, REMOVE SOILED CLOTHES/SHOES. WASH WITH SOAP
& WATER. INHALE-REMOVE TO FRESH AIR & PROVIDE OXYGEN IF HARD TO
BREATH. G IVE CPR IF NOT BREATHING. GET MEDICAL ATTENTION.
INGEST-DO NOT INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY
KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO LUNGS.
GET MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:-40F,-40C
Autoignition Temp:Autoignition Temp Text:UNK
Lower Limits:1.0
Upper Limits:7.8
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, DRY CHEMICAL.
DO NOT USE WATER DIRECTLY, PRODUCT WILL FLOAT & REIGNITE ON
SURFACE.
Fire Fighting Procedures:DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL
BUNKER GEAR INCLUDING A NIOSH POSITIVE PRESSURE SELF CONTAINED
BREATHING APPARATUS. COOL CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR ACCUMULATING
IN LOW AREAS & TRAVELING ALONG THE GROUND AWAY FROM THE HANDLING
SITE. DO NOT WELD, HEAT OR DRILL NEAR CONTAINER.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT, ELIMINATE SOURCES
OF IGNITION, ISOLATE AREA & DENY ENTRY. DIKE TO RETAIN LARGE SPILL.
REMOVE WITH VACUUM TRUCK OR PUMP TO STORAGE/SALVAGE VESSEL. SOAK UP
RESIDUE WITH INERT MATERIAL & FLUSH AREA WITH WATER TO REMOVE
RESIDUE

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA AWAY FROM SOURCES OF IGNITION. ALL HANDLING EQUIPMENT MUST BE
GROUNDED TO PREVENT SPARKING.
Other Precautions:DANGER. EXTREMELY FLAMMABLE. AVOID ALL IGNITION
SOURCES & STRONG OXIDIZING AGENTS. HARMFUL OR FATAL IF SWALLOWED.
DO NOT SIPHON GAS BY MOUTH. FOR USE AS A MOTOR FUEL ONLY. DO NOT
USE AS A CLEANING SOL VENT OR FOR OTHER NON-MOTOR FUEL USE.

Respiratory Protection:UNDER CONDITIONS OF POTENTIAL HIGH EXPOSURE, USE
A NIOSH/MSHA APPROVED RESPIRATOR IS RECOMMENDED, PER CURRENT 29 CFR
1910.134 OR 29 CFR 1910.1028 USE EITHER AN ATMOSPHERE-SUPPLYING
RESPIRATOR OR AIR-P URIFYING RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:NITRILE RUBBER, VITON/NEOPRENE
Eye Protection:WEAR CHEMICAL GOGGLES.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. WEAR IMPERVIOUS
PROTECTIVE TYPE WORK CLOTHING (NITRILE RUBBER, POLYVINYL ALCOHOL,
NEOPRENE)
Work Hygienic Practices:WASH AFTER HANDLING & BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
NOTE TO PHYSICIAN: IF MORE THAN 2.0 ML PER KG HAS BEEN INGESTED &
VOMITING HAS NOT OCCURRED, EMESIS SHOULD BE INDUCED WITH MEDICAL
SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS TO PREVENT ASPIRATION.
IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX, CONVULSION, ETC OCCUR
BEFORE EMESIS, GASTRIC LAVAGE SHOULD BE CONSIDERED.

HCC:F2
Boiling Pt:B.P. Text:100-425F
Vapor Pres:7-14.5 PSI
Vapor Density:3.5
Spec Gravity:0.72-0.76
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRONZE COLOR; CLEAR AND BRIGHT LIQUID. HYDROCARBON
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES. PREVENT
VAPOR ACCUMULATION.
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS CAN BE FORMED UPON COMBUSTION.

Waste Disposal Methods:PRODUCT RECOVERY & RECYCLING IS RECOMMENDED.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.